if i buy one of these rs components psu's for my gx4000 +c4cpc will i be able to use it to power my newly purchased cpc 464 with scart lead or are the voltages / pins totally different?
GX4000 can be powered with either a 9V or a 5V power supply.
The 9V is the one you get (in fact it is 11V) by default with a GX4000, using the scart or modulator output. The 9V power (5.5/2.1mm) plug is the one close to the SCART plug
The 5V is only used when powered from a Plus monitor, using the DIN video output. The 5V power (5.5/2.5mm) plug is the one on left when looking at the SCART plug.
The 464 only uses 5V (5.5/2.1mm) and you should not use the 9V on it.
So your question is far from being dumb

, and the answer is no !